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Synthesis and Characterization of a Chemically-Activated Novel Mesoporous Silica for Cobalt Decontamination from Polluted Water

Sina Matavos-Aramyan1 * and Sadaf Soukhakian1

Corresponding author Email: s.matavos@gmail.com

DOI: http://dx.doi.org/10.12944/CWE.14.2.12

Mesoporous silica was synthesized by a chemical process and its efficiency was investigated for removal of cobalt (Co2+) ions from contaminated water in a laboratory scale. The characteristics of synthesized mesoporous were analyzed by SEM/TGA. Optimal conditions were determined for important parameters such as solution pH, the absorbent dose, the initial Co2+ concentration, and contact time by a single-variable method through the batch experiments. The SEM results confirmed the synthesized silica had high porosity with a honeycomb-like structure. The results showed that with an increasing adsorbent dose and contact time to the optimum, the efficiency of Co2+ adsorption increased. However, with increasing concentration of Co2+, the removal efficiency decreased. At optimal contact time (8 h), 85 % of Co2+ was removed. The maximum adsorption efficiency at pH =7, initial Co2+ concentration of 5 ppm, and at the adsorbent dose 0.3 g/50 ml, was 89%. The study of adsorption isotherm and kinetic models showed that the adsorption process followed the Freundlich isotherm (R2 = 0.9359) and the second-order kinetic model (R2=0.999). Therefore, the synthesized mesoporous silica presented a chemical adsorption mechanism for Co2+ removal from aqueous media and can be utilized in wastewater treatment containing divalent heavy metals such as Co2+.


Adsorption; Cobalt Decontamination; Heavy Metal; Kinetic; Mesoporous Silica; Polluted Water

Copy the following to cite this article:

Matavos-Aramyan S, Soukhakian S. Synthesis and Characterization of a Chemically-Activated Novel Mesoporous Silica for Cobalt Decontamination from Polluted Water. Curr World Environ 2019; 14(2). DOI:http://dx.doi.org/10.12944/CWE.14.2.12

Copy the following to cite this URL:

Matavos-Aramyan S, Soukhakian S. Synthesis and Characterization of a Chemically-Activated Novel Mesoporous Silica for Cobalt Decontamination from Polluted Water. Curr World Environ 2019; 14(2). Available from: https://bit.ly/2kj2T3n